| 1 | –John Barry & His Orchestra | A Man Alone (Theme From The Ipcress File) | 2:29 |
| 2 | –The Walker Brothers | Deadlier Than The Male | 2:32 |
| 3 | –The Ventures | Arabesque | 2:30 |
| 4 | –Dusty Springfield | The Look Of Love (Theme From Casino Royale) | 3:31 |
| 5 | –Red Price & His Combo* | Theme From Danger Man | 2:07 |
| 6 | –Vikki Carr | The Silencers | 2:58 |
| 7 | –Al Caiola | Secret Agent Man | 2:26 |
| 8 | –Astrud Gilberto | Who Needs Forever (Theme From The Deadly Affair) | 2:50 |
| 9 | –The Challengers | Theme From The Man From U.N.C.L.E. | 1:51 |
| 10 | –Nancy Sinatra | The Last Of The Secret Agents | 2:46 |
| 11 | –Lalo Schifrin & His Orchestra* | Mission: Impossible | 2:34 |
| 12 | –The Supremes | Dr Goldfoot And The Bikini Machine | 2:22 |
| 13 | –Billy Strange | Our Man Flint | 2:06 |
| 14 | –Matt Monro | Wednesday's Child (Theme From The Quiller Memorandum) | 2:37 |
| 15 | –Bob Crane, His Drums And Orchestra | Theme From Get Smart | 1:55 |
| 16 | –Cleo Laine & Ray Ellington | We Should've (Theme From Modesty Blaise) | 2:54 |
| 17 | –Johnny & The Hurricanes* | The James Bond Theme (Dr No) | 2:15 |
| 18 | –Wynton Kelly | Burke's Law Theme | 2:11 |
| 19 | –Susan Maughan | Where The Bullets Fly | 2:30 |
| 20 | –Brian Fahey & His Orchestra* | High Wire (Theme From Danger Man) | 2:19 |
| 21 | –Sarah Vaughan | Bye Bye (Theme From Peter Gunn) | 1:52 |
| 22 | –Jimmy Smith | Theme From Where The Spies Are | 2:56 |
| 23 | –Shirley Bassey | The Liquidator | 2:20 |
| 24 | –Roland Shaw & His Orchestra* | I Spy | 2:12 |
| 25 | –Smokey Robinson & The Miracles | Come Spy With Me | 2:56 |